I would do it by reducing the saturation on the whole photo, then using the sponge tool to saturate selected areas. No idea if there's a better way though.
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less stressful way: layer mask - duplicate layer>layer mask>destaurate>select brush and spray away.as long as you have selected the masked layer (layers palette and its white) and your brush is black you will start to mask the top layer leaving the bottom layer showing through, get it wrong and inverse you brush to white and spray your mistake back to how it was, and correct, if you zoom right in you get it supurbly accurate. adjust brush to suite.